Batch Number: FRAMECPSR
Product Name: Cocamidopropyl betaine
Product Number: 5060330630570
Brand: Naturallythinking
Supplier:
UK:
Naturallythinking, Unit 2 Mill Lane Trading Estate, Mill Lane, Croydon, CR0 4AA
EU: NTEU Ltd (HE 426545), Nikis 1, Anthoupoli, 2350, Nicosia, Cyprus
Contact Telephone: 020 38563588
Contact Email: support@naturallythinking.eu
2.1 Classification of the substance or mixture
CLASSIFICATION (EC 1272/2008)
2.2 Label elements According to Regulation (EC) No. 1272/2008 (CLP)
2.2.1 Label elements
GHS Product Identifier: Cocamidopropyl betaineHazard pictogram(s)
HAZARD STATEMENTS
PRECAUTION STATEMENTS
Inci: Cocamidopropyl betaine
Cas: 61789-40-0
Einecs: 263-058-8
3.1. Substances
N.A.
3.2. Mixtures
Product type and use: Sufactants
Hazardous components within the meaning of the CLP regulation and related classification:
| Qty | Name | Ident. Number | Classification |
|---|---|---|---|
| >= 30% - < 40% | Cocamidopropyl betaine | CAS: 147170-443 EC: 931333-8 REACH: 01-2119489410-39-XXX |
3.3/1 Eye Dam.1 H318 4.1/C3 Aquatic Chronic 3 H412 |
| >= 1% - < 3% | Coconut fatty acids | CAS: 61788-47-4 EC: 262-978-7 |
3.3/2 Eye Irrit. 2 H319 3.2/2 Skin Irrit. 2 H315 |
| >= 0.25% - < 0.5% | Cocco, N-[3- (dimetilamino)propil] ammide | CAS: 68140-01-2 EC: 268-771-8 |
3.1/4 Oral Acute Tox. 4H320 4.1/A1 Aquatic Acute 1 H400 |
4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. OBTAIN IMMEDIATE MEDICAL ATTENTION. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose off safely.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately. Protect uninjured eye.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: None
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons: None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases. Burning produces heavy smoke.
5.3. Advice for firefighters Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up Wash with plenty of water.
6.4. Reference to other sections See also section 8 and 13
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Storage recommended at room temperature Keep away from food, drink and feed. Incompatible materials: None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s) None in particular
8.1. Control parameters
No occupational exposure limit available
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374)
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with medium /high efficiency for solid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Thermal Hazards: None Environmental exposure controls:
None
Appropriate engineering controls:
None
9.1. Information on basic physical and chemical properties
| Properties | Value | Method | |
|---|---|---|---|
| Appearance and colour | LIQUID YELLO | -- | -- |
| Odour | Characteristic | -- | -- |
| Odour threshold | N.A. | -- | -- |
| pH | 5 | -- | -- |
| Melting point / freezing point | -5 degrees C | -- | -- |
| Initial boiling point and boiling range | 100 degrees C | -- | -- |
| Flash point: | > 100 degrees C | -- | -- |
| Evaporation rate: | N.A. | -- | -- |
| Soild / gas flammability | N.A. | -- | -- |
| Upper / lower flammability | N.A. | -- | -- |
| Vapour pressure | N/A/ | -- | -- |
| Vapour density | N.A. | -- | -- |
| Relative density | 1.05 | -- | -- |
| Solubility in water | soluble | -- | -- |
| Solubility in oil | insoluble | -- | -- |
| Partition coefficient (n-octanol/water) | N.A. | -- | -- |
| Auto-ignition temperature | N.A. | -- | -- |
| Decomposition temperature | N.A. | -- | -- |
| Viscosity | N.A. | -- | -- |
| Explostive properties | N.A. | -- | -- |
| Oxidising properties | N.A. | -- | -- |
9.2. Other information
| Properties | Value | Method | |
|---|---|---|---|
| Miscibility | N.A. | -- | -- |
| Fat Solubility | N.A. | -- | -- |
| Conductivity | N.A. | -- | -- |
| Substance Groups relevant properties | N.A. | -- | -- |
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.
11.1. Information on toxicological effects
Toxicological information of the product:
a) acute toxicity
Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation
Not classified
Based on available data, the classification criteria are not met
c) serious eye damage/irritation
The product is classified: Eye Dam. 1 H318
d) respiratory or skin sensitisation
Not classified
Based on available data, the classification criteria are not met
e) germ cell mutagenicity
Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity
Not classified
Based on available data, the classification criteria are not met
g) reproductive toxicity
Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure
Not classified
Based on available data, the classification criteria are not met
i) STOT-repeated exposure
Not classified
Based on available data, the classification criteria are not met
j) aspiration hazard
Not classified
Based on available data, the classification criteria are not met
Toxicological information of the main substances found in the product:
Cocamidopropyl betaine - CAS: 147170-44-3
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat
8100 mg/kg
c) serious eye damage/irritation:
Test: Eye Irritant - Species: Rabbit
Positive
d) respiratory or skin sensitisation:
Test: Skin Sensitization - Species: Guinea pig
Negative
e) germ cell mutagenicity:
Test: Mutagenesis - Species: Rabbit Negative
Coconut fatty acids - CAS: 61788-47-4
Acute oral toxicity LD50 (rat) > 2000 mg/Kg
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
The product is classified: Aquatic Chronic 3 - H412
Cocamidopropyl betaine - CAS: 147170-44-3
a) Aquatic acute toxicity:
Endpoint: LC50 - Species: Fish 25 mg/l - Duration h: 25
Endpoint: EC50 - Species: Daphnia 45 mg/kg - Duration h: 45
12.2. Persistence and degradability
None
Biodegradability: Readily biodegradable - Test: N.A. - Duration: N.A. - %: N.A. - Notes:
Regulation (EC) No. 648/2004
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None
13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.
14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards Marine pollutant:
No
14.6. Special precautions for user
N.A.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
N.A.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications:
Where applicable, refer to the following regulatory provisions :
Directive 2012/18/EU (Seveso III)
Regulation (EC) nr 648/2004 (detergents).
Dir. 2004/42/EC (VOC directive)
Provisions related to directive EU 2012/18 (Seveso III):
Seveso III category according to Annex 1, part 1 None
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for the mixture. Substances for which a Chemical Safety Assessment has been carried out: None
Text of phrases referred to under heading 3:
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life
| Hazard class and hazard category | Code | Description |
| Actue Tox. 4 | 3.1/4 | Acute toxicity (oral), Category 4 |
| Skin Irrit. 2 | 3.2./2 | Skin irritation, Category 2 |
| Eye Dam. 1 | 3.3/1 | Serious eye damage, Category 1 |
| Eye Irrit. 2 | 3.3/2 | Eye irritation, Category 2 |
| Aquatic Acute 1 | 4.1/A1 | Acute aquatic hazard category 1 |
| Aquatic Chronic 3 | 4.1/C3 | Chronic (long term) aquatic hazard, category 3 |
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
| Classification according to Regulation (EC) Nr. 1272/2008 | Classification procedure |
| Eye Dam. 1, H318 | Calculation method |
| Aquatic Chronic 3, H412 | Calculation method |
Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
This MSDS cancels and replaces any preceding release.
GMO Declaration
We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material
To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.
Animal Testing Declaration
UK: As set out under the conditions in Schedule 34 - Amendment of Regulation (EC) No 1223/2009 and related amendments of The Product Safety and Metrology etc. (Amendment etc.) (EU Exit) Regulations 2019 neither the cosmetic nor its component product has been tested on animal purposes
EU:As set out in under the conditions in 1223/2009. Art. 15 Nar. Parliament and the Council of the EU 952/2013 neither the cosmetic nor its component product has been tested on animal purposes
WE DO NOT TEST ANY OF OUR PRODUCTS ON ANIMALS AND NEVER HAVE, WE PREFER TO RELY ON OUR KNOWLEDGE OF ESSENTIAL OILS, INGREDIENTS, PLANTS, FLOWERS AND ESTABLISHED TECHNICAL INFORMATION AND PROFESSIONALS TO ENSURE EFFECTIVE AND SAFE PRODUCTS.
We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.
Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.
We do not conduct any form of animal testing.
We do not commission any form of animal testing from a third party.
We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006
If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions