Batch Number: FRAMECPSR
Product Name: Climbazole
Product Number: 5060330639238
Brand: Naturallythinking
Supplier:
UK:
Naturallythinking, Unit 2 Mill Lane Trading Estate, Mill Lane, Croydon, CR0 4AA
EU: NTEU Ltd (HE 426545), Nikis 1, Anthoupoli, 2350, Nicosia, Cyprus
Contact Telephone: 020 38563588
Contact Email: support@naturallythinking.eu
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4, Oral - H302
Acute aquatic toxicity, Category 1 - H400
Chronic aquatic toxicity, Category 1 - H410
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms
Signal word:
Warning
Hazard statements:
H302 Harmful if swallowed.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P391 Collect spillage.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Contains: CLIMBAZOLE.
2.3 Other hazards
No data available
Inci: Climbazole
Cas: 38083-17-9
Einecs: 253-775-4
3.1 Substances
| Chemical Characterisation | Molecular Weight | Total Formula | CAS No. | EINECS-No. | Reach Registration No. |
| Climbazole | 292,76 g/mol | C15-H17-Cl-N2-O2 | 38083-17-9 | 253-775-4 | 01-2119615553-43-0000 |
3.2 Mixtures
Hazardous components: Not applicable
4.1 Description of first aid measures
General advice:
Move out of dangerous area.
Never give anything by mouth to an unconscious person.
Inhalation:
Move to fresh air.
Skin contact:
If symptoms persist, call a physician.
Eye contact:
Immediately flush eye(s) with plenty of water.
Ingestion:
Clean mouth with water and drink afterwards plenty of water.
Prevent vomiting if possible.
If a person vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person.
If accidentally swallowed obtain immediate medical attention.
4.2 Most important symptoms and effects, both acute and delayed
No data available
4.3 Indication of any immediate medical attention and special treatment needed
No data available
5.1 Extinguishing media
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media which shall not be used for safety reasons:
High volume water jet
5.2 Special hazards arising from the substance or mixture:
Specific hazards during firefighting:
Do not use a solid water stream as it may scatter and spread fire.
Do not allow run-off from fire fighting to enter drains or water courses.
5.3 Advice for firefighters
Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus.
Further information:
In the event of fire and/or explosion do not breathe fumes.
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions:
Ensure adequate ventilation.
Use personal protective equipment.
6.2 Environmental precautions
Environmental precautions:
Should not be released into the environment.
Avoid subsoil penetration.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up:
Pick up and transfer to properly labelled containers.
Use mechanical handling equipment.
Dam up.
Additional advice:
Local authorities should be advised if significant spillages cannot be contained.
6.4 Reference to other sections
For personal protection see section 8.
7.1 Precautions for safe handling
Advice on safe handling:
Dispose of rinse water in accordance with local and national regulations.
For personal protection see section 8.
Advice on protection against fire and explosion:
When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Store in original container.
Keep container tightly closed in a dry and well-ventilated place.
To maintain product quality, do not store in heat or direct sunlight.
Advice on common storage:
No special restrictions on storage with other products.
Other data:
No decomposition if stored and applied as directed.
7.3 Specific end use(s)
Cosmetic ingredient
8.1 Control parameters
none
DNEL:
Climbazole:
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 0,3 mg/m3
End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 4,28 mg/kg bw/day
PNEC:
Climbazole:
Compartment: Fresh water
Value: 0,00052 mg/l
Compartment: Fresh water sediment
Value: 0,29 mg/kg dry weight (d.w.)
Compartment: Marine water
Value: 0,000052 mg/l
Compartment: Marine sediment
Value: 0,029 mg/kg dry weight (d.w.)
Compartment: Sewage treatment plant
Value: 100 mg/l
Compartment: Soil
Value: 0,64 mg/kg dry weight (d.w.)
8.2 Exposure controls
Engineering measures
none
Personal protective equipment
Respiratory protection: Half mask with a particle filter P2 (EN 143)
Hand protection: Wear chemicals-resistant gloves, e.g. safety gloves of chloroprene Level 2 or of butyl rubber Level 6.
Eye protection: Safety glasses
Skin and body protection: Lightweight protective clothing
Hygiene measures: Do not breathe dust or spray mist. Wash hands before breaks and immediately after handling the product.
Protective measures: Do not breathe dust.When using do not eat, drink or smoke.
Form: White powder
10.1 Reactivity
Reacts with Strong oxidising agents and acids
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
None known
10.4 Conditions to avoid
High temperatures
10.5 Incompatible materials
Strong oxidising agents. Strong acids
10.6 Hazardous Decomposition Product(s)
None known
No toxicological data available
12.1 Toxicity
(Fish) (96hrs): NOEC> 0.4mg/l (> limit of solubility)(Stearyl alcohol)
(Daphnia magna) (48hrs): EC50 > 0.01 mg/L (> limit of solubility)(Cetyl alcohol)
(Algae) (72hrs): EC50 > 0.01 mg/l (> limit of solubility)(Cetyl alcohol)
12.2 Persistence and degradability
Readily biodegradable.
12.3 Bioaccumulative potential (96 hrs)
The product has moderate potential for bioaccumulation.
12.4 Mobility in soil
This product is predicted to degrade in soil.
12.5 Results of PBT and vPvB assessment
Not classified as PBT or vPvB.
12.6 Other adverse effects
None recorded
13.1 Waste treatment methods
Material to be disposed of as hazardous waste. Normal disposal is via incineration operated by an accredited disposal contractor. Consult an accredited waste disposal contractor or the local authority for advice.
13.2 Additional Information
None
14.1 Land transport (ADR/RID)
UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.
14.2 Sea transport (IMDG)
UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.
14.3 Air transport (ICAO/IATA)
UN number: Not classified according to the United Nations ‘Recommendations on the Transport of Dangerous Goods’.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU regulations: EC Standards 82/242 and 82/243/EEC (Detergents) : This product is > 90% biodegradable in water.
15.1.2 National regulations: None assigned
15.2 Chemical Safety Assessment: No Chemical Safety Assessment (CSA) has been carried out
References:
European Chemicals Agency
European Chemicals Bureau
European Regulations and Directives
Published chemical directories
Suppliers’ safety data sheets
UK Health and Safety Executive
US Environmental Protection Agency
Risk Phrases
R38: Irritating to skin.
R41: Risk of serious damage to eyes.
Safety Phrases
S25: Avoid contact with eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39: Wear eye/face protection.
Hazard statement(s)
H315: Causes skin irritation.
H318: Causes serious eye damage.
Precautionary statement(s)
P262: Do not get in eyes, on skin, or on clothing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
GMO Declaration
We declare that at present all our regisered and commercially available ingredients, extracts, oils, plants and skincare products are derived by traditional plant breeding methods. We do not have any ingredient, extract, oil or skincare product from genetically modified material
To the best of our knowledge, the information contained in the sheet is correct. However, we cannot accept responsibility for any consequences from its use.
Animal Testing Declaration
UK: As set out under the conditions in Schedule 34 - Amendment of Regulation (EC) No 1223/2009 and related amendments of The Product Safety and Metrology etc. (Amendment etc.) (EU Exit) Regulations 2019 neither the cosmetic nor its component product has been tested on animal purposes
EU:As set out in under the conditions in 1223/2009. Art. 15 Nar. Parliament and the Council of the EU 952/2013 neither the cosmetic nor its component product has been tested on animal purposes
WE DO NOT TEST ANY OF OUR PRODUCTS ON ANIMALS AND NEVER HAVE, WE PREFER TO RELY ON OUR KNOWLEDGE OF ESSENTIAL OILS, INGREDIENTS, PLANTS, FLOWERS AND ESTABLISHED TECHNICAL INFORMATION AND PROFESSIONALS TO ENSURE EFFECTIVE AND SAFE PRODUCTS.
We believe there is already a “safe” and known group of product ingredients used in the cosmetics industry which leave enough scope to be creative and innovative in product formulation without the need for anymore animal testing on new experimental ingredients.
Our suppliers each also agree to not to carry out animal testing on the products and ingredients we purchase. We have a self-imposed cut-off date of 2006 (this was the date our cosmetic formulations came into being) although in reality our suppliers normally have animal testing dates far in excess of this or have never tested at all.
We do not conduct any form of animal testing.
We do not commission any form of animal testing from a third party.
We operate a fixed cut-off date for animal testing and ingedients, which means we will not use any ingredient that has been tested or retested on animals for cosmetics purposes since January 1, 2006
If we find that a company is involved in animal testing in anyway that purchases from us, then we will cease supply immediately. It is a term and condition that by purchasing from Naturallythinking you will not involve yourself or your company in any form of Animal Testing, any violation of this will be dealt with as per any violation of our terms and condtions